WebIn contrast, the [Cu2(pyz)(CN)2] sheets in isomer 2 can be viewed as a classical (6,3)-topological brick wall layer, which are also penetrated by [Cu(CN)]∞ chains in the … Web[Cu (SCN)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and 1-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651 (4) A in 1 is the...

Using cuprophilicity as a multi-responsive chromophore

WebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu 2 (ophen) 2] 2 (Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and synthesized a series of such [M 2 L 2] 2 structures by varying the d 10 metal and/or the ligand (M=Cu I or Ag I, L=ophen or obpy; Hobpy=1H-[2,2′]bipyridinyl-6-one), and have … Webintertrimer cuprophilicity.14 The computed gross populations of HOMO and LUMO in the [Cu6(Pz)6] trimer dimer are listed in Table S6, while the contours of the frontier orbitals for the [Cu6 (Pz)6] with single-crystal geometry is shown in Figs. 1g and 1h. high rise style

A luminescent supramolecular Cu2I2(NH3)2-sandwiched …

WebModulating the Extent of Anisotropic Cuprophilicity via High Pressure with Piezochromic Luminescence Sensitization. Zhou Lu , Cynthia M. Archambault , +7 authors Hao Yan Biology WebCuprophilicity, a still elusive concept: a theoretical analysis of the ligand-unsupported Cu I –Cu I interaction in two recently reported complexes Josep-M. Poblet and M. Bénard, … WebJan 7, 2005 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract. high rise studio apartments